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904L Stainless Steel Plate (UNS N08904 / 1.4539)

904L stainless steel plate is a low-carbon super-austenitic grade (UNS N08904 / 1.4539) carrying roughly 25% nickel, 4.5% molybdenum and 1.5% copper. That copper content is what gives it such strong resistance to sulfuric acid and other reducing acids. A PREN of about 34 also means it stands up to chloride pitting far better than 316L. It's supplied to ASTM A240/B625.

PREN 34UNS N08904W.-Nr. 1.4539
NSReviewed by the Nandini Steel Engineering Team
At a glance N08904

Solution-treated flat product, mill-certified to EN 10204 3.1/3.2.

Nickel23-28%
Molybdenum4.0-5.0%
Copper1.0-2.0%
Chromium19-23%
PREN34
Density7.95 g/cm3
Held ex-stock, immediate dispatch with a mill test certificate.
◆Ex-stock, immediate dispatch
◈MTC EN 10204 3.1 / 3.2
▣To EN 10204 traceable
⬡Mill plate: Aperam · Outokumpu · Jindal
904L super-austenitic stainless plate stencilled Ultra 904L, as supplied for 904L Stainless Steel Plate (UNS N08904 / 1.4539)
Mill-marked 904L plate, held ex-stock for sulfuric-acid and chloride service.

Key takeaways: 904L plate at a glance

  • Designation: UNS N08904, Werkstoff 1.4539, a copper-bearing super-austenitic stainless steel, not your standard 300-series austenitic.
  • Why it exists: roughly 1.5% copper and about 4.5% molybdenum hand it a signature resistance to sulfuric acid and other reducing acids, exactly the conditions where 316L and 316 corrode.
  • PREN ~34: resists chloride pitting and crevice attack well above 316 and 316L.
  • Chloride SCC: that high nickel content, roughly 25%, pushes the stress-corrosion-cracking threshold up. The result: 904L holds up far better than 316L in hot chloride service.
  • Supplied as plate: to ASTM A240 / ASME SA-240 and ASTM B625 / ASME SB-625, ex-stock. Every order ships with an EN 10204 3.1/3.2 mill test certificate.

What is 904L stainless steel plate?

904L is a fully austenitic, low-carbon stainless steel (UNS N08904, Werkstoff 1.4539) that sits in the super-austenitic stainless steel family. Its defining feature is a deliberately high alloy content, about 25% nickel, 4.5% molybdenum, 20% chromium and, unusually, 1–2% copper. That copper addition is what separates 904L from conventional grades: it suppresses corrosion in reducing acids such as sulfuric acid, which attack chromium-only stainless steels.

As plate, 904L is the grade a specifier reaches for once 316L has hit its limit in acid or chloride service, though a nickel-base alloy such as Alloy 825 or 625 would be overkill for the duty. The full 904L grade hub covers the alloy across all forms. Plate is the annealed, descaled flat product used for vessels, linings, tube sheets and heavy fabrications.

Chemical composition

Composition for UNS N08904 flat product per ASTM A240 (weight %, balance iron):

ElementSymbolContent (wt %)
CarbonC≤ 0.020
ChromiumCr19.0 – 23.0
NickelNi23.0 – 28.0
MolybdenumMo4.0 – 5.0
CopperCu1.0 – 2.0
ManganeseMn≤ 2.0
SiliconSi≤ 1.0
PhosphorusP≤ 0.045
SulfurS≤ 0.035
IronFeBalance

The role of copper and molybdenum

Molybdenum drives pitting and crevice resistance, almost every point of PREN beyond what chromium provides comes from the roughly 4.5% Mo content. Copper does quieter work. It slows the corrosion rate in reducing environments, which is why 904L performs so well in dilute-to-mid-concentration sulfuric acid. Extra-low carbon, at or below 0.02%, keeps chromium in solution so the plate resists intergranular attack after welding. That limits sensitization between 425 and 815 °C.

Mechanical properties

Minimum room-temperature properties for solution-annealed 904L plate per ASTM A240:

PropertyMinimum value
Tensile strength490 MPa (71 ksi)
Yield strength (0.2% offset)220 MPa (32 ksi)
Elongation in 50 mm35% min
Hardness≤ 90 HRB

904L work-hardens a fair amount during cold forming. Plan your forming forces and spring-back with that in mind, and solution-anneal whenever heavy cold work precedes corrosive service.

Physical properties

PropertyValue
Density7.95 g/cm³
Melting range~1300 – 1390 °C
Thermal conductivity (20 °C)~11.5 W/m·K
Mean coefficient of thermal expansion (20–100 °C)~15.3 µm/m·°C
Elastic modulus~190 GPa
Magnetic responseNon-magnetic (austenitic)

The 7.95 g/cm³ density figure is what gets used in the plate weight calculation below.

Corrosion behavior & PREN: why 904L plate exists

904L earns its spot almost entirely on corrosion resistance. On the orderable PREN ladder it sits well above the common austenitics and close to lean duplex: 304 (~18) < 316/316L (~24) < 904L (~34) < Duplex 2205 (~35), with Incoloy 825 around 31–40 and super-duplex 2507 near 43. Three mechanisms decide whether 904L plate is the right call, and the sections below cover each one.

Sulfuric-acid resistance

The copper addition gives 904L its signature sulfuric-acid resistance across dilute and intermediate concentrations where 316L suffers rapid general attack. Before upgrading, check the actual acid concentration and temperature against the published 904L iso-corrosion curves, within those limits 904L is a cost-justified answer for sulfuric-acid plant, pickling and acid-regeneration duty.

Pitting & crevice corrosion: PREN ~34

With a PREN of about 34 (PREN = Cr + 3.3·Mo + 16·N), 904L resists chloride-driven pitting and crevice corrosion at chloride levels and temperatures that would initiate attack on 316L. That margin makes it suitable for brackish water, bleach and process streams where pitting and crevice corrosion are the controlling failure modes.

Chloride stress-corrosion cracking

Austenitic stainless steels are vulnerable to chloride stress-corrosion cracking, and 316L cracks under hot chloride loads. The high ~25% nickel content of 904L raises the SCC threshold substantially, so 904L outperforms 316L in hot chloride environments, one of the main reasons it is chosen for heat-exchanger and vessel plate in chloride-bearing service.

Equivalent grades & designations

SystemDesignation
UNSN08904
Werkstoff (W.-Nr.)1.4539
ENX1NiCrMoCu25-20-5
BS904S13
AISI904L
JISNo direct equivalent

For cross-system matching on the PO and MTC, check the UNS/Werkstoff UNS/W.Nr/JIS cross-reference table.

904L plate vs the alternatives: when to choose it

904L sits partway up an upgrade ladder. The real question is rarely whether 904L is good; it's whether 904L is the right rung. See the table below for where each neighbor wins.

GradePREN (approx.)Choose when…
316 / 316L~24Mild chlorides, no reducing acid, do not over-spec.
904L~34Sulfuric/reducing acid or high chloride beyond 316L, below a 6-Mo need.
Duplex 2205~35Similar pitting resistance with higher strength and chloride-SCC resistance; weight-critical or structural duty.
Alloy 20~30+Hot concentrated sulfuric acid beyond 904L limits.
254 SMO (6-Mo)~43Seawater and severe chloride service where 904L pits.
Titanium–Oxidising chlorides and wet chlorine where stainless fails.

904L vs 316L

316L carries 2–3% molybdenum; 904L roughly doubles that figure and adds copper. The practical upshot is a sharp jump in resistance to reducing acids and chlorides. For the full breakdown of cost versus service life, see our 904L vs 316L comparison.

904L vs Duplex 2205

904L and Duplex 2205 land in the same ballpark on PREN. Duplex pulls ahead on strength and holds up better against chloride-SCC. 904L, by contrast, is fully austenitic. That makes it easier to form into complex vessel shapes, and it has the edge in reducing acids where copper matters. For the full breakdown, see the 904L vs duplex 2205 comparison.

904L vs 316, Alloy 20, 254 SMO & titanium

Choose 316 only for mild duty. Step past Alloy 20 when copper-bearing 904L already covers the acid, and move to 254 SMO or super-duplex only where seawater-grade chloride resistance is genuinely required. Reserve titanium for oxidising-chloride service outside the stainless envelope.

Forms, sizes & thickness ranges

Nandini Steel keeps 904L plate on hand across the common hot-rolled thickness range, cut and supplied to order. Every plate ships ex-stock, so dispatch is immediate.

AttributeTypical range
Thickness3 mm – 50 mm (heavier on request)
Widthup to 2500 mm
Lengthup to 6000 mm (cut to size)
ConditionSolution-annealed, descaled

Other 904L forms

For thinner gauges and continuous product, check out 904L sheet and 904L coil. The grade also comes as plate, along with sheet and coil, through the 904L grade hub.

Plate weight & how to calculate

904L plate weight follows directly from its 7.95 g/cm³ density:

Weight (kg) = thickness (mm) × width (m) × length (m) × 7.95

Worked example: a 10 mm × 1.25 m × 2.5 m plate.

10 × 1.25 × 2.5 × 7.95 = 248.4 kg.

ThicknessWeight per m² (kg)
3 mm23.85
6 mm47.70
10 mm79.50
20 mm159.00

For other sizes use the weight calculator.

Finishes

904L plate usually comes hot-rolled, annealed and pickled, the No.1 finish, which gives the clean, oxide-free surface that corrosive service demands. Thinner plate can be furnished with a 2B cold-rolled finish when a smoother surface is called for. The finish should match the duty. For acid and chloride vessels, a pickled No.1 surface is standard.

Standards & specifications complied

904L plate meets ASTM A240 and its pressure-vessel counterpart ASME SA-240, both chromium-nickel stainless plate specifications. N08904, as a higher-alloy flat product, also needs to satisfy ASTM B625 / ASME SB-625.

ASTM A240 vs ASTM B625/SB-625 for N08904

A240/SA-240 sits inside the stainless plate standard and covers N08904; it's the call-out people usually reach for on vessel plate. B625/SB-625, on the other hand, is the dedicated spec for N08904 and its super-austenitic flat-product relatives. Both reference the same chemistry and the same annealed condition. Specify whichever one your code or client demands, and Nandini Steel will certify to it.

Testing, inspection & certification

Every 904L plate order ships with an EN 10204 3.1 mill test certificate, or MTC, with 3.2 available on request. It reports the actual heat chemistry and mechanical results checked against the ordered standard, and full heat and cast traceability is stamped right onto the plate. Intergranular-corrosion testing per ASTM A262, positive material identification (PMI) and ultrasonic testing (UT) can be arranged on request. All material is genuine mill plate from established producers such as Aperam, Outokumpu, Jindal, POSCO, Nippon Steel and JFE, supplied with the original mill certification.

Applications of 904L plate by industry

904L plate gets specified any time reducing acids and chlorides go beyond what 316L can handle:

Welding & fabrication of 904L plate

904L needs an over-alloyed filler to hold weld-metal corrosion resistance to the same standard as the base plate. ER385 (Avesta 904L) works for matching duty; for joints where integrity matters more, a nickel-base filler such as FM 625 is the better choice. Heat input has to stay controlled, and interpass temperatures need to be kept low.

When heavy cold forming comes before corrosive service, solution-anneal at 1070–1150 °C, then quench rapidly to restore the microstructure. For the full procedure, see how to weld 904L.

Pricing & how we quote

Nandini Steel doesn't publish fixed price bands for 904L plate. Nickel and molybdenum prices move constantly, so quotes get built against your exact thickness, size and quantity instead. Send over your plate list for a current RFQ. Material sits ex-stock, ready for immediate dispatch, and ships with the EN 10204 3.1/3.2 mill test certificate.

From the Nandini Steel Engineering Team

The most common spec mistake with 904L is jumping straight to Alloy 20, 625, or titanium for sulfuric-acid or high-chloride service, when 904L's copper-bearing chemistry, roughly 4.5% Mo and a PREN near 34, already handles it for less money. Check the acid concentration and temperature against the 904L iso-corrosion limits before you pay for an upgrade you don't need.

On the flip side, don't under-spec 904L in places where 6-Mo (254 SMO) or super-duplex is truly called for.

FAQ

Is 904L good for sulfuric acid?
Yes. That 1–2% copper in 904L exists for one reason: it fights off reducing acids. That's what gives it solid performance in dilute-to-intermediate sulfuric acid, a range where 316L corrodes fast. Don't skip the numbers, though. Check your exact acid concentration and temperature against the published 904L iso-corrosion curves, because very hot, concentrated acid can push you into Alloy 20 or something stronger.
What is the PREN of 904L plate?
904L plate carries a PREN (pitting resistance equivalent number) of roughly 34, worked out as Cr + 3.3·Mo + 16·N. That puts it well ahead of 316L (~24) and near Duplex 2205 (~35). In practice, it shrugs off chloride pitting and crevice attack at levels that would eat through standard austenitic grades like 316.
Is 904L better than 316L?
For acid and chloride service, yes, it holds up well. 904L roughly doubles the molybdenum content of 316L and brings in copper and nickel besides, which is why it stands up to sulfuric acid, chloride pitting and stress-corrosion cracking so much better. If the duty is mild and chlorides aren't a concern, though, 316 stays the economical pick. Check the full 904L vs 316L comparison before you commit to an upgrade.
What standards does 904L plate meet?
904L plate is supplied to ASTM A240 / ASME SA-240 for stainless plate, and separately to ASTM B625 / ASME SB-625, which is the dedicated N08904 flat-product specification. The chemistry covered is identical across both, and both apply to the solution-annealed condition. Each plate ships with an EN 10204 3.1/3.2 mill test certificate that certifies whichever standard was ordered.
How do you calculate 904L plate weight?
Multiply the thickness in mm by the width in meters, then by the length in meters, then by the density of 7.95 g/cm³: weight (kg) = thickness × width × length × 7.95. Take a 10 mm × 1.25 m × 2.5 m plate, and you land at roughly 248 kg. For other sizes and quantities, run the numbers through the online weight calculator.
What filler is used to weld 904L plate?
904L gets welded with an over-alloyed filler so the weld can match the base metal's corrosion resistance. That means ER385, a 904L-type wire, for matching service, or a nickel-base filler like FM 625 when the joint demands more. Heat input needs to stay low. After heavy cold work, solution-anneal to bring corrosion performance back.

Request a quote for 904L plate

Nandini Steel has been around since 2003, an ISO 9001:2015-certified stockist and supplier with certified specialist status in 904L, Alloy 28, Incoloy 800 and Hastelloy plate. Every bit of 904L plate sits ex-stock, ready to ship right away. Each order ships with an EN 10204 3.1/3.2 mill test certificate. Send over your plate list, and we'll get you a current RFQ.

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